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Synthesis and characterization of silver(I) salts with amino methyl pyridines containing phosphines: novel complex formation upon ratio, anion, or ligand changes.

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dc.contributor.advisor Klausmeyer, Kevin Kenneth, 1969-
dc.contributor.author Amawi, Rema Mouawya.
dc.contributor.other Baylor University. Dept. of Chemistry and Biochemistry. en
dc.date.copyright 2008-05
dc.identifier.uri http://hdl.handle.net/2104/5180
dc.description.abstract Phosphorus ligands are well recognized for stabilizing metal complexes in a variety of oxidation states and coordination geometries.1 Compounds with pyridyl containing phosphines have been investigated with carbinol groups in the past; this work studies the pyridyl amines. The focus of this research is to explore the different binding properties as the position of the nitrogen changes on the ligand, as well as changing the silver(I) salts binding to the ligand such as the BF₄⁻ , OTf⁻ and the tfa⁻ anions. The synthesis and characterization of two new ligands that are from the same family have been looked at, and the synthesis of novel silver(I) complexes involving these ligands have been explored. All of the compounds produced have been characterized by X-ray crystallography, NMR spectroscopy, fluorescence, and elemental analyses. en
dc.rights Baylor University theses are protected by copyright. They may be viewed from this source for any purpose, but reproduction or distribution in any format is prohibited without written permission. Contact librarywebmaster@baylor.edu for inquiries about permission. en
dc.subject Coordination compounds -- Synthesis. en
dc.subject Ligands. en
dc.subject Amines. en
dc.subject Silver salts. en
dc.subject Pyridine. en
dc.subject Phosphine. en
dc.title Synthesis and characterization of silver(I) salts with amino methyl pyridines containing phosphines: novel complex formation upon ratio, anion, or ligand changes. en
dc.type Thesis en
dc.description.degree M.S. en
dc.rights.accessrights Baylor University access only en
dc.contributor.department Chemistry and Biochemistry. en


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